Rod, main, & head bolts - yes
Lug nuts on any import or an American car newer than mid 80's. Yes
Exotic unfamiliar engine parts like Cam Phasers or some other unusual item that looks like it could warp under too much pressure, I look up and torque to spec too.

Anything else I will torque with experience and the industry standard spiral sequence.

I never thought of anything else having a torque spec until I watched a terminator movie and Arnold used a torque wrench on a starter. I thought that's weird and then it hit me, oh yeah there is probably a spec for everything. LOL

I also only use Red threadlocker (Permanent) and never blue (Temporary). Especially on cam bolts, even if it isn't required.

I also incrementally torque nearly everything and never tighten any one bolt until all the bolts are started and run most of the way in. I can not tell you how many newbie mechanics just start popping in bolts & tighten away, and then they have to loosen them all to get the last few in.