SCT. it DOES work.
the chips are junk, don't use them. or the stupid resistor tricks.
but Sean Powell aka "Hemifever" (www.hemifevertuning.com and
hemifever@aol.com) can get you Hp gains over stock with nothing more than a custom tune. start adding bolt-ons like headers, intakes, etc and the power levels go up more.
he can also change shift points, rev limiters, speed limiters, etc.
now, as far as gaining MPGs, it's not very likely. you MAY see marginal gains, but only if you drive it like a granny on her sunday drive to nowhere.
He can tune 5.2, 5.9 on OBD-II computers, and he can tune 4.7s and the 3rd gen Hemi's (I think he may have issues with the 6.4 crate motors, but the 5.7 and 6.1 is in the capabilities of the software)
shoot him an email telling him you're interested in a tuner, and want to know more, I can pretty much guarantee that he'll respond to you within 3 hours, and more than likely within 1 hour. He has outstanding customer service.