Engine Oil Myths - GM TechLink: "A higher level of ZDP was good for flat-tappet valve-train scuffing and wear, but it turned out that more was not better. Although break-in scuffing was reduced by using more phosphorus, longer-term wear increased when phosphorus rose above 0.14%. And, at about 0.20% phosphorus, the ZDP started attacking the grain boundaries in the iron, resulting in camshaft spalling."
Excessive phosphorus (the antiwear component of ZDDP -
Zinc
Dialkyl
Dithio
Phosphate) tends to cause camshaft spalling. 0.20% Phosphorus is the same as 2000 ppm of phosphorus. Phosphorus should not exceed 1400 ppm or 0.14% in engine oil for maximum wear protection, which is why the old API CI-4/SL 15W-40 HDEOs typically had 1300-1350 ppm of phosphorus.
It's better and cheaper to use an engine oil formulated with enough ZDDP than to mix your own by guessing at how much ZDDP to add. The new API CK-4
HDEOs typically have 1000-1200 ppm of phosphorus.
See
Camshaft Spalling