Posted By: 360view
secret of ancient Roman concrete mix - 07/22/23 09:25 AM
https://www.sciencealert.com/we-finally-know-why-ancient-roman-concrete-stood-the-test-of-time
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One of the questions in mind was the nature of the lime used. The standard understanding of pozzolanic concrete is that it uses slaked lime. First, limestone is heated at high temperatures to produce a highly reactive caustic powder called quicklime, or calcium oxide.
Mixing quicklime with water produces slaked lime, or calcium hydroxide: a slightly less reactive, less caustic paste. According to theory, it was this slaked lime that ancient Romans mixed with the pozzolana.
Based on the team's analysis, the lime clasts in their samples are not consistent with this method. Rather, Roman concrete was probably made by mixing the quicklime directly with the pozzolana and water at extremely high temperatures, by itself or in addition to slaked lime, a process the team calls "hot mixing" that results in the lime clasts.
"The benefits of hot mixing are twofold," Masic said.
"First, when the overall concrete is heated to high temperatures, it allows chemistries that are not possible if you only used slaked lime, producing high-temperature-associated compounds that would not otherwise form. Second, this increased temperature significantly reduces curing and setting times since all the reactions are accelerated, allowing for much faster construction."
And it has another benefit: The lime clasts give the concrete remarkable self-healing abilities.
When cracks form in the concrete, they preferentially travel to the lime clasts, which have a higher surface area than other particles in the matrix. When water gets into the crack, it reacts with the lime to form a solution rich in calcium that dries and hardens as calcium carbonate, gluing the crack back together and preventing it from spreading further.
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sample quote
One of the questions in mind was the nature of the lime used. The standard understanding of pozzolanic concrete is that it uses slaked lime. First, limestone is heated at high temperatures to produce a highly reactive caustic powder called quicklime, or calcium oxide.
Mixing quicklime with water produces slaked lime, or calcium hydroxide: a slightly less reactive, less caustic paste. According to theory, it was this slaked lime that ancient Romans mixed with the pozzolana.
Based on the team's analysis, the lime clasts in their samples are not consistent with this method. Rather, Roman concrete was probably made by mixing the quicklime directly with the pozzolana and water at extremely high temperatures, by itself or in addition to slaked lime, a process the team calls "hot mixing" that results in the lime clasts.
"The benefits of hot mixing are twofold," Masic said.
"First, when the overall concrete is heated to high temperatures, it allows chemistries that are not possible if you only used slaked lime, producing high-temperature-associated compounds that would not otherwise form. Second, this increased temperature significantly reduces curing and setting times since all the reactions are accelerated, allowing for much faster construction."
And it has another benefit: The lime clasts give the concrete remarkable self-healing abilities.
When cracks form in the concrete, they preferentially travel to the lime clasts, which have a higher surface area than other particles in the matrix. When water gets into the crack, it reacts with the lime to form a solution rich in calcium that dries and hardens as calcium carbonate, gluing the crack back together and preventing it from spreading further.
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