Capacitors are a marketing gimick. They just don't store enough power or recharge quickly enough to be of any use on a serious system.
If your alternator can't keep up in the first place, how is adding another power sucking device going to help?
If you want some serious reserve capacity for your stereo or your hotrod, check out one of these.
They'll smoke any cap you try to put in a system as a bandaid, and start your car good too. Check out thes discharge rates theses batteries pump out. They make smaller ones too.
http://www.odysseybatteries.com/battery/pc2150.htm