Not difficult at all..Just make sure you put paper towel in the ports on the heads when you take it off, clean the head surface with a wirebrush...get all the crud off...hit it with some brake cleaner...blow the paper towels with compressed air to get rid of the debris and pull out the paper towels.....
The next part is up for debate. I just lay the valley pan down on the bare head and put the intake gasket on the valley pan, then the manifold. Work in a cross hatch pattern when installing the bolts to make sure your holes are aligned then torque them down to the spec.
I don't use any sealant on it because the head gets really hot, it will burn out eventually and you will have a leak point...Other will chime in to and tell me I am wrong...